Methods for producing rubber mixtures

ABSTRACT

The invention relates to processes for the production of microgel-containing rubber mixtures, to rubber mixtures obtainable by the processes, to processes for the production of vulcanizates, and also to vulcanizates after the vulcanization process, in particular in the form of tires, parts of tires, or industrial rubber items.

The invention relates to processes for the production of microgel-containing rubber mixtures, to rubber mixtures obtainable by these processes, to processes for the production of vulcanizates, and also to vulcanizates after the vulcanization process, in particular in the form of tires, parts of tires, or industrial rubber items. The processes of the invention improve the physical and mechanical properties of unvulcanized and vulcanized rubber mixtures comprising silica and microgels, in particular microgels based on rubbers, by carrying out the reaction with sulfur-containing organosilicon compounds sequentially, i.e. in a plurality of separate stages.

It is known that silica-containing rubber mixtures can be used for the production of tire treads with a good combination of rolling resistance properties, wet slip resistance properties, and abrasion properties, these being the properties demanded for car tire treads. If the desired combination of properties is to be achieved, it is important to obtain good dispersion of the silica and to couple it effectively to the rubber matrix during the vulcanization process. Sulfur-containing organic silanes are used for this purpose during production of the mixture (e.g.: DE-A-24 47 614; U.S. Pat. No. 4,709,065; EP-A-0 501 227; EP-A-99 074; DE-A-3 813 678 and also EP-A-447 066).

These patents use silica in combination with sulfur-containing organic silanes during production of the mixture. The silanes are added to the mixture with the silica in the same mixing step in order to hydrophobize the silica and to achieve good dispersion within the mixture. Use of the sulfur-containing organosilanes during the vulcanization process also achieves good coupling of the silica to the rubber matrix.

These patents do not contain any teaching about the combination of silica with microgels or about sequential silane addition.

The use of microgels in compounded rubber materials is also known and is described by way of example in the following patents or applications: EP-A-405 216, EP-A-0 575 851, DE-A-197 01 489, EP-A-1 149 866, EP-A-1 149 867, EP-A-1 152 030, EP-A-1 298 166, EP-A-1 245 630, and EP-A-1 291 369.

EP-A-405 216 teaches the production and use of gels based on polychloroprene. EP-A-0 575 851 teaches the production and use of gels based on polybutadiene, and EP-A-0 854 171 teaches the production of gels using groups which are active in vulcanization processes. According to the teaching of these patents, the use of gels is advantageous for achieving a good wet slip resistance/rolling resistance relationship. An index for this combination of properties is the difference in rebound resilience values at 70° C. and 23° C. (Δ(R₇₀−R₂₃)). However, the mechanical properties of the vulcanizates produced using these gels are not satisfactory.

The use of silanes (EP-A-1 063 259/U.S. Pat. No. 6,399,706) improves the mechanical properties of microgel-containing compounded rubber materials. The compounded materials are based on NR and comprise only gel, without any further fillers. The compounded materials are produced in a two-stage process. According to the teaching of this patent, additions of 75 phr of gel (without silica) give very high differences in the rebound resilience values between 70° C. and 23° C. (maximum values of 43% and 45% in 3^(rd) mixture series). However, the mechanical properties of the vulcanizates, and in particular the product (σ₃₀₀×ε_(b)) of modulus for 300% elongation (σ₃₀₀) and elongation at break (ε_(b)), are inadequate.

Further improvements, in particular in the mechanical properties of the vulcanizates, expressed as product σ₃₀₀×ε_(b), are successfully achieved via the combination of silica, microgel, and carbon black in rubber-compounded materials (EP-A-1 401 951/US-A-2003/092827). The best values are found for addition of 1 phr of the microgel (σ₃₀₀×ε_(b)=5106). The product σ₃₀₀×ε_(b) becomes less satisfactory if the content of microgel is further increased. In the presence of silica, the highest values for the differences in rebound resilience values Δ(R₇₀−R₂₃) are 30% (mixture series A) and 36% (mixture series B). The greatest difference in the rebound resilience values Δ(R₇₀−R₂₃) is 38%, observed for the silica-free compounded material No. 8 in mixing series B.

According to the teachings of EP-A-1 149 866, EP-A-1 149 867, EP-A-1 152 030, EP-A-1 298 166, EP-A-1 245 630, EP-A-1 291 369, compounded rubber materials are produced which comprise silica in combination with gel. These patents give no teaching relating to the sequential addition of silane. Nor do the patents mentioned give any information relating to the 300 modulus (σ₃₀₀). It is therefore impossible to use the product (σ₃₀₀×ε_(b)) to make any comparison between the mechanical properties of the vulcanizates produced by the teaching of these patents with other data accessible in the patent literature, etc.

Further improvement in the properties of compounded rubber materials which comprise silica and rubber gels requires further improvement in the vulcanizate properties, in particular in the product of modulus at 300% elongation and elongation at break (σ₃₀₀×ε_(b)), without any impairment of the differences in rebound resilience values Δ(R₇₀−R₂₃).

It has now been found that this aim can be achieved using compounded rubber materials in particular based on SBR and BR, where these comprise, as fillers, at least one oxidic filler containing hydroxy groups, a particular example being silica, and rubber gel, when the mixture is produced in a plurality of stages, where the addition of the sulfur-containing organic silane is divided over at least two mixing stages.

The invention therefore provides a process for the production of rubber mixtures which encompasses the mixing of the following components:

a) one or more rubber components, b) one or more oxidic fillers containing hydroxy groups, c) one or more microgels containing hydroxy groups, d) one or more sulfur-containing organosilicon compounds, e) if appropriate, one or more vulcanizing agents, f) if appropriate, one or more rubber additives, characterized in that the sulfur-containing organosilicon compound is added in at least two separate portions, where the first portion encompasses at least 30% by weight of the total amount of the sulfur-containing organosilicon compound.

Rubber Component a)

The rubber components a) of the invention preferably include those based on dienes, particular examples being rubbers which contain double bonds and which comprise practically no gel content, and which DIN/ISO 1629 terms R-rubbers. These rubbers have double bonds in the main chain. Examples of rubber components preferably used are those based on

NR: natural rubber SBR: styrene/butadiene rubber BR: polybutadiene rubber IR: polyisoprene SIBR: styrene/isoprene rubber NBR: nitrile rubber IIR: butyl rubber (isobutene/isoprene rubber) HNBR: hydrogenated nitrile rubber SNBR: styrene/butadiene/acrylonitrile rubber CR: polychloroprene XSBR: carboxylated styrene/butadiene rubber XNBR: carboxylated butadiene/acrylonitrile rubber ENR: epoxydized natural rubber ESBR: epoxydized styrene/butadiene rubber and mixtures of these.

In the invention, rubber components containing double bonds also include those which DIN/ISO 1629 terms M-rubbers, having double bonds in side chains alongside the saturated main chain. Among these is, for example, EPDM.

Rubber components preferred in the invention are: NR, BR, IR, SBR, IIR, and EPDM.

Particular preference is given to natural rubber (NR) and to synthetic polyisoprene (IR), and also to styrene/diolefin rubbers, in particular styrene/diene rubbers, in particular styrene/butadiene rubbers, and also to mixtures of these rubbers.

Styrene/diolefin rubbers (in particular butadiene rubbers) mean not only solution SBR rubbers, abbreviated to SSBR, but also emulsion SBR rubbers, abbreviated to: ESBR. SSBR means rubbery polymers which are produced in a solution process, based on vinylaromatics and on conjugated dienes (H. L. Hsieh, R. P. Quirk, Marcel Dekker Inc. New York, Basle 1996; I. Franta Elastomers and Rubber Compounding Materials; Elsevier 1989. pages 73-74, 92-94; Houben-Weyl, Methoden der Organischen Chemie [Methods of organic chemistry], Thieme Verlag, Stuttgart, 1987, volume E 20, pages 114 to 134; Ullmann's Encyclopedia of Industrial Chemistry, Vol A 23, Rubber 3. Synthetic, VCH Verlagsgesellschaft mbH, D-69451 Weinheim, 1993, S. 239-364, and also (FR 2 295 972)). Suitable vinylaromatic monomers are styrene, o-, m-, and p-methylstyrene, industrial methylstyrene mixtures, p-tert-butylstyrene, α-methylstyrene, p-methoxystyrene, vinylnaphthalene, divinylbenzene, trivinylbenzene, and divinylnaphthalene. Styrene is preferred. The content of copolymerized vinylaromatic is preferably from 5 to 50% by weight, more preferably from 10 to 40% by weight. Suitable diolefins are 1,3-butadiene, isoprene, 1,3-pentadiene, 2,3-dimethylbutadiene, 1-phenyl-1,3-butadiene, and 1,3-hexadiene. Preference is given to 1,3-butadiene and isoprene. The content of copolymerized dienes is from 50 to 95% by weight, preferably from 60 to 90% by weight. The content of vinyl groups in the copolymerized diene is from 10 to 90%, and the content of 1,4-trans double bonds is from 20 to 80%, and the content of 1,4-cis double bonds is complementary to the entirety of vinyl groups and 1,4-trans double bonds. The vinyl content of the SSBR is preferably >20%.

The polymerized monomers and the various diene configurations usually have random distribution in the polymer. The definition of SSBR (A) is also intended to include rubbers having block-type structure, these being termed integral rubber (K.-H. Nordsiek, K.-H. Kiepert, G A K Kautschuk Gummi Kunststoffe 33 (1980), no. 4, 251-255).

SSBR is intended to mean not only linear rubbers but also branched or end-group-modified rubbers. By way of example, FR 2 053 786 and JP-A-56-104 906 are mentioned here. The branching agent used preferably comprises silicon tetrachloride or tin tetrachloride.

Rubber component a) for the rubber mixtures of the invention is in particular produced by anionic solution polymerization, i.e. by means of catalyst based on alkali metal or on alkaline earth metal, in an organic solvent.

The vinylaromatic/diolefin rubbers polymerized in solution advantageously have Mooney values of from 20 to 150 Mooney units, preferably from 30 to 100 Mooney units. In particular, the high-molecular-weight ESBR grades with Mooney values>80 MU can comprise amounts of from 30 to 100 parts by weight of oils, based on 100 parts by weight of rubber. The oil-free SSBR rubbers have glass transition temperatures of from −80° C. to +20° C., determined by differential thermal analysis (DSC).

ESBR means rubbery polymers which are produced in an emulsion process based on vinylaromatics, on conjugated dienes and, if appropriate, on further monomers (Ullmann's Encyclopedia of Industrial Chemistry, Vol A 23, Rubber 3. Synthetic, VCH Verlagsgesellschaft mbH, D-69451 Weinheim, 1993, pp. 247-251). Vinylaromatics are styrene, p-methylstyrene, and alpha-methylstyrene. Dienes are in particular butadiene and isoprene. Further monomers are in particular acrylonitrile. The contents of vinylaromatics are from 10 to 60% by weight. The glass transition temperature is from −50 to +20° C. (determined by means of DSC), and the Mooney values are from 20 to 150 Mooney units. In particular, the high-molecular-weight ESBR grades with Mooney values>80 MU can comprise amounts of from 30 to 100 parts by weight of oils, based on 100 parts by weight of rubber. The oil-free SSBR rubbers have glass transition temperatures of from −80° to +20° C., determined by differential thermal analysis (DSC).

Polybutadiene (BR) encompasses in particular two different classes of polybutadiene. The first class has 1,4-cis content of at least 90%, and is produced with the aid of Ziegler/Natta catalysts, based on transition metals. It is preferable to use catalyst systems based on Ti, Ni, Co, and Nd (Houben-Weyl, Methoden der Organischen Chemie [Methods of organic chemistry], Thieme Verlag, Stuttgart, 1987, volume E 20, pages 114 to 134; Ullmann's Encyclopedia of Industrial Chemistry, Vol A 23, Rubber 3. Synthetic, VCH Verlagsgesellschaft mbH, D-69451 Weinheim, 1993, pp. 239-364). The glass transition temperature of this polybutadiene is preferably <−90° C. (determined by means of DSC).

The second class of polybutadiene is produced using Li catalysts, and has vinyl contents of from 10% to 80%. The glass transition temperatures of these polybutadiene rubbers are in the range from −90 to +20° C. (deter wined by means of DSC).

Polyisoprene (IR) has at least 70% 1,4-cis content. The materials used are not only synthetic 1,4-cis polyisoprene (IR) but also natural rubber (NR). IR is synthesized either by means of lithium catalysts or else with the aid of Ziegler/Natta catalysts (Houben-Weyl, Methoden der Organischen Chemie [Methods of organic chemistry], Thieme Verlag, Stuttgart, 1987, volume E 20, pages 114 to 134; Ullmann's Encyclopedia of Industrial Chemistry, Vol. A 23, Rubber 3. Synthetic, VCH Verlagsgesellschaft mbH, D-69451 Weinheim, 1993, pp. 239-364). It is preferable to use natural rubber.

IR also includes polyisoprene, known as 3,4-polyisoprene, having glass transition temperatures in the range from −20 to +30° C.

In the invention, the rubber component is preferably selected from the group consisting of: styrene/butadiene rubbers, polybutadiene, and polyisoprene, and these rubbers can also have been extended using mineral oils.

The ratio of the other components to the rubber components a) is usually stated by using the relative unit phr (parts per hundred parts rubber (i.e. component a)). The usual amounts used per 100 parts by weight of rubber components a) are from 5 to 100 parts by weight of the oxidic filler b) containing hydroxy groups (corresponding to from 5 to 100 phr), from 1 to 30 phr, preferably from 5 to 25 phr, of the microgels c), from 0.1 phr to 15 phr, preferably from 0.2 phr to 10 phr, of the sulfur-containing organosilicon compound d), preferably bis(triethoxysilylpropyl) tetrasulfide or bis(triethoxysilylpropyl) disulfide, from 0.1 to 15 phr, preferably from 0.1-10 phr, of the vulcanizing agents e), and also from 0.1 to 200 phr of the rubber additives f). The mixtures of the invention preferably also comprise amounts of from 1 to 100 phr of carbon black.

Oxidic Filler b) Containing Hydroxy Groups

The oxidic filler b) used, containing hydroxy groups, preferably comprises a silicone-containing oxidic filler containing hydroxy groups, in particular silica. These are in particular hydrophilic silicas which in particular bear hydroxy groups at the surface.

Silica (Ullmann's Encyclopedia of Industrial Chemistry, VCH Verlagsgesellschaft mbH, D-69451 Weinheim, 1993, “Silica”, pp. 635-645) is in particular used in the form of fumed silica (ibid., pp. 635-642) or in the form of precipitated silica (ibid. 642-645), but the invention gives preference to the precipitated silica here. The specific surface area of the precipitated silicas is from 5 to 1000 m²/g, determined by the BET method, preferably from 20 to 400 m²/g. They are obtained by treating waterglass with inorganic acids, preference being given to use of sulfuric acid. The silicas can also, if appropriate, take the form of mixed oxides with other metal oxides, examples being those of Al, Mg, Ca, Ba, Zn, Zr or Ti.

The invention preferably uses silicas having specific surface areas of from 5 to 1000 m²/g, and more preferably from 20 to 400 m²/g, in each case determined by the BET method. The preferred amounts used of the oxidic filler b) containing hydroxy groups in the invention are from 20 to 150 phr, preferably from 30 to 120 phr, based on 100 phr (parts per 100 parts rubber), and the oxidic filler b) containing hydroxy groups here makes up at least 30%, preferably at least 50%, of the filler content, based on the total amount of fillers used.

Microgels c)

The microgels that can be used in the vulcanizable composition of the invention have glass transition temperatures in the range from −75° C. to +120° C. (determined by means of DSC).

The microgel used in the vulcanizable composition of the invention is usually a crosslinked microgel based on homopolymers or on copolymers. The microgels used in the invention are therefore usually crosslinked homopolymers or crosslinked copolymers. The terms homopolymers and copolymers are well known to the person skilled in the art and are explained by way of example in Vollmert, Polymer Chemistry, Springer 1973.

The glass transition temperatures of the microgels are generally higher by from 1° C. to 10° C. than the glass transition temperatures of the corresponding uncrosslinked homo- or copolymers, and, in a first approximation, the glass transition temperatures of the microgels here rise in proportion to the degree of crosslinking. The glass transition temperatures of weakly crosslinked microgels are only about 1° C. higher than those of the corresponding homo- or copolymers. The glass transition temperatures of highly crosslinked microgels can be up to 10° C. higher than the glass transition temperatures of the corresponding uncrosslinked homo- or copolymers. The following equations can in particular be used to calculate the glass transition temperatures of the underlying uncrosslinked copolymers (see, for example: U. Eisele, Einführung in die Polymerphysik [Introduction to polymer physics], Springer-Verlag):

Tg _(Copolymer) =w ₁ *Tg ₁ +w ₂ *Tg ₂ +w ₃ *Tg ₃+ . . .

Tg_(copolymer): glass transition temperature of copolymer in ° C. W₁: proportion by weight of homopolymer 1 Tg₁: glass transition temperature of homopolymer 1 in ° C. W₂: proportion by weight of homopolymer 2 Tg₂: glass transition temperature of homopolymer 2 in ° C. W₃: proportion by weight of homopolymer 3 Tg₃: glass transition temperature of homopolymer 3 in ° C.

$\frac{1}{{Tg}_{Copolymer}} = {\frac{w_{1}}{{Tg}_{1}} + \frac{w_{2}}{{Tg}_{2}} + \frac{w_{3}}{{Tg}_{3}} + \ldots}$

Tg_(copolymer): glass transition temperature of copolymer in K W₁: proportion by weight of homopolymer 1 Tg₁: glass transition temperature of homopolymer 1 in K W₂: proportion by weight of homopolymer 2 Tg₂: glass transition temperature of homopolymer 2 in K W₃: proportion by weight of homopolymer 3 Tg₃: glass transition temperature of homopolymer 3 in K

Good results are achieved in these calculations if the following glass transition temperatures of the corresponding homopolymers are used as starting point: polybutadiene: −80° C., polyisoprene: −65° C., polychloroprene: −39° C., polystyrene: +100° C., polyacrylonitrile: +100° C., poly-alpha-methylstyrene: +115° C., poly(2-hydroxyethyl methacrylate): +75° C. and poly(2-hydroxypropyl methacrylate): +80° C. Further glass transition temperatures have been published in J. Brandrup, E. H. Immergut, Polymer Handbook, Wiley & Sons 1975.

The microgels used in the vulcanizable composition of the invention advantageously have the following insoluble fraction in toluene at 23° C. (“gel content”): at least 70% by weight, preferably at least 80% by weight, and particularly preferably at least 90% by weight. This fraction insoluble in toluene is determined in toluene at a temperature of 23°. 250 mg of the microgel here are swollen in 25 ml of toluene for 24 hours, with shaking at 23° C. The insoluble fraction is isolated and dried after centrifuging at 20 000 rpm. Gel content is calculated from the quotient calculated from the dry residue and from the starting weight, and is stated in percent by weight.

The microgels used in the vulcanizable composition of the invention usually have a swelling index (“SI”) of less than 80, preferably less than 60, and in particular less than 40, in toluene at 23° C. The swelling index of the microgels is particularly preferably in the range from 1 to 30, in particular in the range from 1 to 20. The swelling index SI is calculated by the following formula from the weight of the solvent-containing microgel swollen in toluene for 24 hours at 23° C. (after centrifuging at 20 000 rpm) and the weight of the dry microgel:

SI=wet weight of microgel/dry weight of microgel.

To determine the swelling index, 250 mg of the microgel is permitted to swell for 24 h in 25 ml of toluene, with shaking. The gel is isolated by centrifuging and is weighed, and is then dried to constant at 70° C., and again weighed.

The glass transition temperatures T_(g) of the microgels used in the vulcanizable composition of the invention are preferably in the range from −90° C. to +150° C., particularly preferably in the range from −80° C. to +120° C.

The range of the glass transition (“ΔT_(g)”) of the microgels used is moreover greater than 5° C., preferably greater than 10° C., particularly preferably greater than 20° C. Microgels having this type of glass transition range do not generally have completely homogeneous crosslinking, in contrast to the completely homogeneous microgels obtained, for example, by radiation crosslinking. The result of this is that there is not an immediate change in modulus from the matrix phase to the disperse phase. The result is that exposure to sudden stress does not lead to break-away phenomena between matrix and disperse phase, and there is therefore an advantageous effect on mechanical properties, swelling behavior, and buckling behavior.

Differential Scanning Calorimetry (DSC) is used to determine the glass transition temperature (T_(g)) and the range of the glass transition (ΔT_(g)) of the microgels. To determine T_(g) and ΔT_(g), two cooling/heating cycles are carried out. T_(g) and ΔT_(g) are determined in the second heating cycle. From 10-12 mg of the selected microgel are used for the determinations, in a DSC specimen container (standard aluminum dish) from Perkin-Elmer. The first DSC cycle is carried out by first cooling the specimen to −100° C. with liquid nitrogen and then heating it at a rate of 20K/min to +150° C. The second DSC cycle is begun by immediately cooling the specimen as soon as its temperature has reached +150° C. The cooling takes place at a rate of about 320 K/min. In the second heating cycle, the specimen is again heated, as in the first cycle, to +150° C. The heating rate in the second cycle is again 20K/min. T_(g) and ΔT_(g) are determined graphically on the DSC curve for the second heating procedure. To this end, three straight lines are drawn in contact with the DSC curve. The 1^(st) straight line is drawn in contact with that part of the DSC curve below T_(g), the 2^(nd) straight line is drawn in contact with that part of the curve running through T_(g) with an inflection point, and the 3^(rd) straight line is drawn in that part of the DSC curve above T_(g). This method gives three straight lines with two intersections. Each of the two intersections is characterized by a characteristic temperature. The glass transition temperature T_(g) is obtained as the average of these two temperatures, and the range of the glass transition ΔT_(g) is obtained from the difference between the two temperatures.

The microgels present in the composition of the invention are in principle known and can be produced in a manner known per se (see, for example. EP-A-0 405 216, EP-A-0 854 171, DE-A 42 20 563, GB-PS 1078400, DE-A-197 01 489, DE-A-197 01 488, DE-A-198 34 804, DE-A-198 34 803, DE-A-198 34 802, EP-A-1 063 259, DE-A-199 39 865, DE-A-199 42 620, DE-A-199 42 614, DE-A-100 21 070, DE-A-100 38 488, DE-A-100 39 749, DE-A-100 52 287, DE-A-100 56 311, and DE-A-100 61 174).

The microgels used in the invention are in particular crosslinked rubber particles based on the following rubbers:

-   BR: polybutadiene, -   ABR: butadiene/acrylic acid-C1-4-alkyl ester copolymers, -   IR: polyisoprene, -   SBR: random styrene-butadiene copolymers having styrene contents of     from >0 to <100 percent by weight, -   X-SBR: carboxylated styrene-butadiene copolymers, -   FKM: fluoro rubber, -   ACM: acrylate rubber, -   NBR: polybutadiene-acrylonitrile copolymers having acrylonitrile     contents of from 5-60 percent by weight, preferably from 10-50     percent by weight, -   X-NBR: carboxylated nitrile rubbers, -   CR: polychloroprene, -   IIR: isobutylene/isoprene copolymers having isoprene contents of     from 0.5-10 percent by weight, -   HNBR: partially and fully hydrogenated nitrile rubbers, -   EPDM: ethylene-propylene-diene copolymers, -   EAM: ethylene/acrylate copolymers, -   EVM: ethylene/vinyl acetate copolymers, -   Q: silicone rubbers, -   AU: polyester urethane polymers, -   EU: polyether urethane polymers. -   ENR: epoxidized natural rubber, or a mixture hereof.

The uncrosslinked microgel starting products are advantageously produced by the following methods:

-   1. crosslinking copolymerization in emulsion (direct polymerization)     using monomers of relatively high functionality, -   2. crosslinking of uncrosslinked latices, e.g. via treatment with     crosslinking agents, e.g. dicumyl peroxide, -   3. redispersion of polymers which are not accessible by emulsion     polymerization, from the corresponding solutions of these polymers,     in organic solvents, and crosslinking, by method 2, of the secondary     latices thus obtained, -   4. functionalization of the microgels obtained by methods 1 to 3,     using suitable methods, or by grafting with suitable monomers.

The microgels (B) are preferably those obtainable by methods 1 and 2. Particular preference is given to those which are produced by crosslinking copolymerization by method 1, in emulsion, where suitable monomers are copolymerized during the crosslinking polymerization process with functionalized, in particular hydroxy-functional, monomers.

When the microgels used in the invention are produced by emulsion polymerization, examples of the monomers used, capable of free-radical polymerization, are the following: butadiene, styrene, acrylonitrile, isoprene, esters of acrylic and methacrylic acid, tetrafluoroethylene, vinylidene fluoride, hexafluoropropene, 2-chlorobutadiene, 2,3-dichlorobutadiene, and also carboxylic acids containing double bonds, e.g. acrylic acid, methacrylic acid, maleic acid, itaconic acid, etc., hydroxy compounds containing double bonds, e.g. hydroxyethyl methacrylate, hydroxyethyl acrylate, hydroxypropyl methacrylate, hydroxypropyl acrylate, hydroxybutyl methacrylate, hydroxybutyl acrylate, amine-functionalized (meth)acrylates, acrolein, N-vinyl-2-pyrrolidone, N-allylurea, and N-allylthiourea, secondary amino (meth)acrylates, such as 2-tert-butylaminoethyl methacrylate, and 2-tert-butylaminoethylmethacrylamide etc.

The rubber gel can be crosslinked directly during the emulsion polymerization process, for example via copolymerization with crosslinking polyfunctional compounds, or can be achieved via subsequent crosslinking, as described below. Direct crosslinking during the emulsion polymerization process is preferred, as mentioned above. Preferred comonomers of relatively high functionality, or polyfunctional comonomers, are compounds having at least two, preferably from 2 to 4, copolymerizable C═C double bonds, e.g. diisopropenylbenzene, divinylbenzene, trivinylbenzene, divinyl ether, divinyl sulfone, diallyl phthalate, triallyl cyanurate, triallyl isocyanurate, 1,2-polybutadiene, N,N′-m-phenylenemaleimide, 2,4-tolylenebis(maleimide), and/or triallyl trimellitate. It is also possible to use the acrylates and methacrylates of polyhydric, preferably di- to tetrahydric C2 to C10 alcohols, such as ethylene glycol, 1,2-propanediol, butanediol, hexanediol, polyethylene glycol having from 2 to 20, preferably from 2 to 8, oxyethylene units, neopentyl glycol, bisphenol A, glycerol, trimethylolpropane, pentaerythritol, sorbitol, with unsaturated polyesters derived from aliphatic di- and polyols, and also maleic acid, fumaric acid, and/or itaconic acid.

Examples include: ethylene glycol di(meth)acrylate, propylene glycol di(meth)acrylate, 1,4-butandiol di(meth)acrylate, 1,6-hexanediol di(meth)acrylate, trimethylolpropane di(meth)acrylate, trimethylolpropane tri(meth)acrylate, etc. The monomers of relatively high functionality can be used alone or in combination. Quantitative proportions of these monomers are, for example, from about 0.01 to 10% by weight, based on the total weight of the microgels.

Examples of direct crosslinking during the polymerization process are described by way of example in: EP-A-1 664 158, EP-A-1 149 866, EP-A-1 149 867, EP-A-1 298 166, EP-A-1 291 369, EP-A-1 245 630.

The crosslinking to give rubber microgels during the emulsion polymerization process can also take place by continuing the polymerization process up to high conversions, or in the monomer feed process, through polymerization using high internal conversions. Another possibility consists in carrying out the emulsion polymerization process in the absence of regulators.

For the crosslinking of the uncrosslinked or of the weakly crosslinked microgel starting products following the emulsion polymerization process, the best method uses the latices which are obtained during the emulsion polymerization process. Natural rubber latices, too, can be crosslinked in this way.

Examples of suitable crosslinking chemicals are organic peroxides, such as dicumyl peroxide, tert-butyl cumyl peroxide, bis(tert-butylperoxyisopropyl)benzene, di-tert-butyl peroxide, 2,5-dimethylhexane 2,5-dihydroperoxide, 2,5-dimethylhex-3-yne 2,5-dihydroperoxide, dibenzoyl peroxide, bis(2,4-dichlorobenzoyl) peroxide, tert-butyl perbenzoate, and also organic azo compounds, such as azobisisobutyronitrile and azobiscyclohexanonitrile, and also di- and polymercapto compounds, such as dimercaptoethane, 1,6-dimercaptohexane, 1,3,5-trimercaptotriazine, and mercapto-terminated polysulfide rubbers, such as mercapto-terminated reaction products of bischloroethylformal with sodium polysulfide.

The ideal temperature for carrying out the post-crosslinking process naturally depends on the reactivity of the crosslinking agent, and can be carried out at temperatures from room temperature to about 180° C., if appropriate under elevated pressure (in which connection see Houben-Weyl, Methoden der organischen Chemie [Methods of organic chemistry], 4^(th) edition, volume 14/2, pages 848). Particularly preferred crosslinking agents are peroxides.

The crosslinking of rubbers containing C═C double bonds to give microgels can also take place in dispersion or emulsion with simultaneous, partial or, if appropriate, complete, hydrdogenation of the C═C double bond, by using hydrazine, as described in U.S. Pat. No. 5,302,696 or U.S. Pat. No. 5,442,009, or, if appropriate, by using other means of hydrogenation, examples being organometal hydride complexes.

If appropriate, particle enlargment can be carried out by agglomeration prior to, during, or after the post-crosslinking process.

The microgels used in the invention have modification by hydroxy groups at locations in particular including the surface of the particles. The hydroxy group content of the microgels is determined in the form of hydroxy number with the dimension mg KOH/g of polymer, by reaction with acetic anhydride and titration of the resultant liberated acetic acid with KOH to DIN 53240. The hydroxyl number of the microgels is preferably from 0.1-100, still more preferably from 1 to 100, mg KOH/g of microgel, and still more preferably from 3 to 70 mg KOH/gram of microgel, and more preferably from 5 to 50 mg KOH/gram of microgel.

A particularly successful method of introducing the hydroxy groups into the microgels used in the invention uses hydroxy compounds containing double bonds, e.g. hydroxyalkyl (meth)acrylates, such as 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, 3-hydroxypropyl (meth)acrylate, 2-hydroxybutyl (meth)acrylate, 3-hydroxybutyl (meth)acrylate, and 4-hydroxybutyl (meth)acrylate, etc.; mono(meth)acrylates of polyoxyalkylene glycol (having from 2 to 23 oxyalkylene units), such as polyethylene glycol, polypropylene glycol, etc.; unsaturated amides containing hydroxy groups, e.g. N-hydroxymethyl(meth)acrylamide, N-(2-hydroxyethyl)(meth)acrylamide, and N,N-bis(2-hydroxyethyl)(meth)acrylamide, etc.; vinylaromatic compounds containing hydroxy groups, e.g. o-hydroxystyrene, m-hydroxystyrene, p-hydroxystyrene, o-hydroxy-alpha-ethylstyrene, m-hydroxy-alpha-methylstyrene, p-hydroxy-alpha-methylstyrene, and p-vinylbenzyl alcohol, etc.; (meth)allyl alcohol compounds, etc.

The expression “(meth)acrylat” in this application always includes the acrylates and methacrylates.

The hydroxy groups can moreover also be obtained via subsequent modification of microgels not containing hydroxy groups.

Microgels preferred in the invention are those based on styrene, on butadiene, and on hydroalkyl (meth)acrylates, e.g. HEMA, which are directly crosslinked with addition of polyfunctional compounds, particular examples being polyacrylates, such as trimethylolpropane triacrylate.

Sulfur-Containing Organosilicon Compounds d)

The sulfur-containing organosilicon compounds d) generally always have one of the following structural elements:

-   -   an organosilicon structural element, in particular an         alkoxysilyl group, preferably a trialkoxysilyl group,     -   a sulfur-containing structural element, in particular moiety         S_(x) of a sulfide or of a polysufide, in which x can be on         average from about 1 to 10, preferably from 1 to 6,     -   a divalent “spacer” group Q, which connects the organosilicon         structural element to the sulfur-containing structural element.

Sulfur-containing organosilicon compounds that can be used are in particular those having the following fundamental structures:

in which x can be on average from 1 to 10, preferably from 1 to 6, R¹, R², and R³ are alkoxy groups preferably having from 1 to 10 carbon atoms, Q is a spacer group, in particular based on aliphatic, heteroaliphatic, aromatic, or heteroaromatic carbon chains having from 1 to 20 carbon atoms, preferably from 1 to 10 carbon atoms, and having 1 to 3 heteroatoms, such as oxygen, sulfur, nitrogen, R⁴ is hydrogen, alkyl, and/or a moiety with the following structures:

in which R⁵ is an aliphatic, heteroaliphatic, cycloaliphatic, aromatic, or heteroaromatic moiety having from 1 to 20, preferably from 1 to 10, carbon atoms, and having from 1 to 3 heteroatoms, such as oxygen, nitrogen, or sulfur.

Preferred sulfur-containing organosilicon compounds are bis(triethoxysilylpropyl polysulfanes) of the following structural formula:

where n=from 2 to 4. Products of this type are commercially available as silane Si 75 (n=2), and as silane Si 69 (n=4) from Degussa.

Advantageous total amounts used of the sulfur-containing organosilicon compounds are from 0.2 phr to 12 phr.

In the invention it is essential that the sulfur-containing organosilicon compounds d) are added in at least two separate portions. Separate means that the addition of the proportions is chronologically separate. The meaning of this in practice is clear to the person skilled in the art, without defining any minimum chronological separation. The chronological separation is at least about 1 minute, and still more preferably at least 20 minutes up to 6 or 8 hours, as a function of the rubber mixture and mixing apparatus. It is preferable that the addition takes place during at least two different mixing stages at elevated temperatures in particular or more than 60° C., between which there is at least one cooling step.

Vulcanizing Agent e)

Vulcanizing agents used in the invention are in particular sulfur or sulfur donors, such as dithiomorpholine (DTDM) or 2-(4-morpholinodithio)benzothiazole (MBSS). Examples of amounts used of sulfur and sulfur donors are from 0.1 to 15 parts by weight, preferably from 0.1-10 parts by weight, based on the total amount of rubber.

Rubber Additives f):

Among the rubber additives used in the invention are in particular the vulcanization accelerators. Examples of suitable vulcanization accelerators are mercaptobenzothiazoles, -sulfenamides, guanidines, thiuram disulfides, dithiocarbamates, thioureas, thiocarbonates, and also dithiophosphates, etc. (Ullmann's Encyclopedia of Industrial Chemistry, VCH Verlagsgesellschaft mbH, D-69451 Weinheim, 1993, vol A 23 “Chemicals and Additives”, pp. 366-417).

The vulcanization accelerators are advantageously not added in a mixing step which uses elevated temperatures and which is carried out for the activation of the oxidic filler containing hydroxy groups, for example of the silica and, respectively, of the microgels, by means of the sulfur-containing organosilicon compounds, because they would lead to premature scorch of the mixture. They are therefore preferably incorporated after addition of the sulfur-containing organosilicon compounds, at temperatures which are preferably below 100° C.

The preferred amounts used of the vulcanization accelerators are from 0.1 to 15 parts by weight, preferably from 0.1-10 parts by weight, based on the total amount of rubber.

The rubber mixtures produced in the invention preferably comprise at least one vulcanization accelerator. The mixtures frequently comprise a plurality of accelerators, if appropriate in combination with activators.

The rubber mixtures produced in the invention preferably comprise further rubber additives known per se.

Among these are in particular also further fillers, a particular example being carbon black, the use of which is preferred in the rubber mixtures produced in the invention.

Carbon blacks (E) produced in the invention, see “carbon” or “carbon black” (Ullmann's Encyclopedia of Industrial Chemistry, VCH Verlagsgesellschaft mbH, D-69451 Weinheim, 1993, vol A 5 “Carbon Black”, pp. 95-158) are preferably produced by the gas black process, furnace black process, lamp black process, and thermal black process, their new ASTM nomenclature being N 110, N 115, N 121, N 125, N 212, N 220, N 231, N 234, N 242, N 293, N 299, S 315, N 326, N 330, N 332, N 339, N 343, N 347, N 351, N 375, N 472, N 539, N 550, N 582, N 630, N642, N 650, N 660, N 683, N 754, N 762, N 765, N 772, N 774, N 787, N 907, N 908 N 990, N 991 S 3 etc. (ASTM D1765 and D2516). The BET surface areas of the carbon blacks used in the invention are preferably from 5 to 200 m²/g.

Amounts preferably used of carbon black in the invention are from 0 to 120 phr, with preference from 1 to 100 phr, still more preferably from 5 to 80 phr.

The total amount of oxidic filler b) containing hydroxy groups and carbon black in the invention is preferably from 20 to 160 phr, with preference from 25 to 140 phr.

Further fillers which are used if appropriate are:

-   -   synthetic silicates, such as aluminum silicate, alkaline earth         metal silicate, such as magnesium silicate or calcium silicate,         with BET surface areas of from 20-400 m²/g and with primary         particle diameters of from 5-400 nm     -   natural silicates, such as kaolin and other naturally occurring         silicas,     -   metal oxides, such as zinc oxide, calcium oxide, magnesium         oxide, aluminum oxide,     -   metal carbonates, such as calcium carbonate, magnesium         carbonate, zinc carbonate,     -   metal sulfates, such as calcium sulfate, barium sulfate,     -   metal hydroxides, such as aluminum hydroxide and magnesium         hydroxide,     -   glass fibers and glassfiber products (slats, strands, or glass         microbeads),     -   thermoplastics (polyamide, polyester, aramid, polycarbonate,         syndiotactic 1,2-polybutadiene and trans-1,4-polybutadiene) and         also cellulose and starch,         all of which are not within the definition of component b).

Further rubber additives encompass antioxidants, antireversion agents, light stabilizers, antiozonants, processing aids, plasticizers, mineral oil, tackifiers, blowing agents, dyes, pigments, waxes, resins, extenders, organic acids, vulcanization retarders, vulcanization activators, such as zinc oxide, stearic acid, and also zinc stearate, metal oxides, and also further filler activators, such as triethanolamine, trimethylolpropane, polyethylene glycol, hexanetriol, aliphatic trialkoxysilanes, or others known in the rubber industry (Ullmann's Encyclopedia of Industrial Chemistry, VCH Verlagsgesellschaft mbH, D-69451 Weinheim, 1993, vol A 23 “Chemicals and Additives”, pp. 366-417).

The amounts used of the rubber additives are conventional and depend inter alia on the intended use. Examples of conventional amounts for individual rubber additives, with the exception of the further fillers, for example in particular carbon black or mineral oil, are from 0.1 to 50 phr.

It is advantageous to produce the mixture in at least two stages, and it is preferable here that, in the first at least two mixing stages, the mixture constituents a)+b)+c), and also 30% to 80%, preferably from 40 to 60%, of the total amount of the sulfur-containing organosilicon compound d) are added to the mixture and thermomechanical treatment is carried out at temperatures which are preferably from 80 to 200° C., more preferably from 120° C. to 190° C., still more preferably from 130° C. to 180° C., for from 1 to 15 min, preferably from 2 to 10 min, where all or part of the total amount of microgel c) is present in the rubber mixture during the first mixing step. In addition to the components mentioned, it is in particular also possible to add further rubber additives in the first mixing step, examples being plasticizers, vulcanization activators, such as zinc oxide, stearic acid, vulcanizing agents, such as sulfur, antioxidants, and also an organic base, such as diphenylphenylguanidine or di-o-tolylguanidine, these preferably not being added in the presence of vulcanizing agent. In order to avoid scorch, it is advantageous that no vulcanization accelerators are added in the first mixing step.

It is advantageous that the rubber mixture obtained in the first mixing stage is cooled to temperatures of <140° C., preferably <100° C., before the remaining amount of sulfur-containing organosilicon compound and the further components are added. It is also possible to store the mixtures at room temperature between the first and second mixing stage.

The second mixing stage preferably comprises addition of the remaining amount of sulfur-containing organosilicon compound to the mixture obtained in the first mixing stage, and thermomechanical treatment at temperatures which are preferably from 80 to 200° C., more preferably from 120° C. to 190° C., still more preferably from 130° C. to 180° C., for from 1 to 15 min, preferably from 2 to 10 min. Further rubber additives can be added in the second mixing stage in addition to the components mentioned, examples being plasticizers, zinc oxide, stearic acid, sulfur, antioxidant, and also an organic base, such as diphenylguanidine or di-o-tolylguanidine, if this has not previously been done in the first mixing step. In order to avoid scorch at the high temperatures, it is again advantageous that no vulcanization accelerators are added in the second mixing step.

It is advantageous that the rubber mixture which is obtained in the second mixing stage is cooled to temperatures<100° C., preferably <80° C., before addition of further components and in particular of the vulcanization accelerator(s). Again, it is possible to store the mixture at room temperature between the second and third mixing stage.

Scorch of the mixture must be avoided during the thermomechanical treatment of the rubber mixture in the first and second mixing step. For this reason, the thermomechanical treatment is carried out without additives which would lead to scorch of the mixture. Addition of vulcanization accelerators and, if appropriate, also of sulfur donors, capped bismercaptans, and also sulfur and, if appropriate, zinc oxide and stearic acid must therefore be carried out at the end of the second mixing step, after cooling of the mixture to temperatures<120° C., preferably <100° C., particularly preferably <80° C.

The accelerators can also be added in a third mixing stage, which is carried out at temperatures<60° C., e.g. on a roll.

Suitable assemblies for producing the mixture are known per se and include by way of example rolls, internal mixers, or else mixing extruders.

The rubber mixtures produced in the invention are preferably vulcanized at temperatures of from 100 to 250° C., preferably 130 to 180° C., if appropriate under a pressure of from 1 to 100 bar.

The rubber mixtures produced in the invention are suitable for the production of various tire components, in particular for tire treads, subtreads, carcasses, sidewalls, reinforced sidewalls for spare tires, apex mixtures, etc., and also for the production of industrial rubber items, such as damping elements, roll coverings, conveyor-belt coverings, drive belts, spinning cops, gaskets, golf-ball cores, shoe soles, etc. The mixtures are particularly suitable for the production of tire treads, subtreads, carcasses, and apex mixtures. Tires or tire parts here also include, for example, treads of summer tires, of winter tires, and of all-season tires, and also treads of car tires and of truck tires.

The following examples illustrate the invention.

EXAMPLES Rubber Gel

The present invention used an SBR gel with T_(g)=−15° C. This gel has an insoluble fraction of 94.8% by weight in toluene. The swelling index in toluene is: 7.35. The hydroxy number is 32.8 mg KOH/g of gel.

The gel was produced by copolymerizing a monomer mixture, the constitution of which is listed in the table below, by using the polymerization conditions disclosed in EP 1 298 166 under the heading “[1]Production of Rubber Gel”, in paragraph [0077].

Quantitative proportions Monomers [parts by weight] Butadiene 44.5 Styrene 46.5 Trimethylolpropane trimethacrylate 1.5 Hydroxyethyl methacrylate 7.5

The gel latex obtained during the polymerization process was further treated and worked up as in EP 1245 630 “Production Example 1: Production of Conjugated Diene-Based Rubber Gel 1” in paragraphs [0103] and [0104].

Variation of Addition Sequence of Microgel and of Sulfur-Containing Organosilicon Compound

Experiment 1 is a comparative example, essentially using silica (80 phr) as filler alongside carbon black (5 phr), without microgel. The silica is activated with bis(triethoxysiliylpropyl monosulfane) (Si 75 from Degussa Hüls AG), and the entire amount of silane is added here in the 1^(st) mixing stage.

Experiment 2 is a comparative example in which the rubber mixture also comprises microgel (20 phr) and also some carbon black (5 phr), alongside silica (80 phr). Silica and microgel are activated with bis(triethoxysilylpropyl monosulfane) (Si 75 from Degussa Hills AG), and the entire amount of silane is added here in the 1^(st) mixing stage.

Experiments 6 and 7 are comparative experiments not within the invention, where only 20% of the total amount of sulfur-containing organosilane are added in the first mixing step. 80% of the total amount of the sulfur-containing organosilane (=sulfur-containing organosilicon compound d)) were added in the second mixing step.

Experiments 3, 4 and 5 of this study are examples of the invention, in which 75% (experiments 3 and 4) and 50% (experiment 5) of the total amount of sulfur-containing organosilane were added in the 1st mixing step. The remaining amount of sulfur-containing organosilane was added in the second mixing step in these examples. In the case of experiment 4, addition of the microgel was also delayed to the 2nd mixing step.

1st mixing stage Compounded material No. 1 2 3 4 5 6 7 Solution SBR ¹⁾ 110 110 110 110 110 110 110 Polybutadiene ²⁾ 20 20 20 20 20 20 20 Microgel ³⁾ — 20 20 — 20 20 — Silica ⁴⁾ 80 80 80 80 80 80 80 Mineral oil ⁵⁾ 7.5 7.5 7.5 7.5 7.5 7.5 7.5 Zinc oxide ⁶⁾ 2.5 2.5 2.5 2.5 2.5 2.5 2.5 Stearic acid ⁷⁾ 1 1 1 1 1 1 1 TMQ ⁸⁾ 1 1 1 1 1 1 1 6 PPD ⁹⁾ 1 1 1 1 1 1 1 Ozone wax ¹⁰⁾ 1.4 1.4 1.4 1.4 1.4 1.4 1.4 Si75 ¹¹⁾ 6.4 6.4 4.8 4.8 3.2 1.3 1.3 Maximum 150 150 150 150 150 150 150 temperature [° C.] Time at max. 6 6 6 6 6 6 6 temperature [min.] Cooling and storage 24 24 24 24 24 24 24 at 23° C. [h] ¹⁾ Buna ® VSL 5025-1 HM from Lanxess Deutschland GmbH (extended with 37.5 phr of mineral oil) ²⁾ Buna ® CB 25 (neodymium polybutadiene) from Lanxess Deutschland GmbH ³⁾ Microgel ⁴⁾ Vulkasil S from Lanxess Deutschland GmbH ⁵⁾ Enerthene 1849-1 ⁶⁾ Rotsiegel zinc white from Grillo Zinkoxid GmbH ⁷⁾ Edenor C 18 98-100 from Cognis Deutschland GmbH ⁸⁾ 2,2,4-trimethyl-1,2-dihydroquinonline, polymerized (Vulkanox ® HS/LG from Lanxess Deutschland GmbH) ⁹⁾ N-1,3-dimethylbutyl-N′-phenyl-p-phenylenediamine (Vulkanox ® 4020/LG from Lanxess Deutschland GmbH) ¹⁰⁾ Antilux ® 654 from RheinChemie GmbH ¹¹⁾ Bis(triethoxysilylpropylmonosulfane) (Si 75 from Degussa Hüls AG)

2nd mixing stage Compounded material No. 1 2 3 4 5 6 7 Mikrogel — — — 20 — — 20 Si75 — — 1.6 1.6 3.2 5.1 5.1 Maximum 150 150 150 150 150 150 150 temperature [° C.] Time at max. 6 6 6 6 6 6 6 temperature [min.] Cooling and storage 24 24 24 24 24 24 24 at 23° C. [h]

3rd mixing stage (roll) Compounded material No. 1 2 3 4 5 6 7 Carbon black ¹²⁾ 5 5 5 5 5 5 5 Sulfur ¹³⁾ 1.9 1.9 1.9 1.9 1.9 1.9 1.9 CBS ^(l4)) 1.9 1.9 1.9 1.9 1.9 1.9 1.9 DPG ¹⁵⁾ 2.3 2.3 2.3 2.3 2.3 2.3 2.3 Maximum <50 <50 <50 <50 <50 <50 <50 temperature [° C.] ¹²⁾ Corax N 234 from Degussa Hüls AG ¹³⁾ Soluble sulfur (Chancel ® 90/95° ground sulfur from Solvay Barium Strontium) ¹⁴⁾ N-Cyclohexyl-2-benzothiazylsulfenamide (Vulkanox ® CZ/C from Lanxess Deutschland GmbH) ¹⁵⁾ Diphenylguanidine (Vulkacit ® D/C from Lanxess Deutschland GmbH)

Mooney viscosity and Mooney relaxation were determined after 10 and 30 sec on the unvulcanized rubber mixture. Experiments 3 and 5 of the invention are found to have lower Mooney viscosities (ML1+1 and ML1+4, in each case at 100° C.), and also lower Mooney relaxation values after 10 and 30 sec, than Comparative Experiments 1 and 2. This means that the mixtures produced in the invention have better processibility than Comparative Experiments 1 and 2.

Testing of mixtures Compounded material No. 1 2 3 4 5 6 7 ML 1 + 1 133.9 116.3 114.6 130 109.7 103.5 114.2 (100° C.) [MU] ML 1 + 4 98.8 99.4 97.3 110.5 92 89.5 97.2 (100° C.) [MU] Mooney 31.6 30.3 29.3 33.2 28.8 27.7 29.4 relaxation/10 sec. [%] Mooney 24.5 23.3 22.5 27.2 22.2 20.9 23.3 relaxation/30 sec. [%]

The vulcanization behavior of the mixtures is studied in a rheometer at 160° C. to DIN 53 529 with the aid of a Monsanto MDR 2000E rheometer. Characteristic data such as F_(a), F_(max), F_(max.)−F_(a), t₁₀, t₅₀, t₉₀ and t₉₅ were thus determined.

The definitions to DIN 53 529, part 3 are:

F_(a): vulcameter value indicated at minimum of crosslinking isotherm F_(max): maximum vulcameter value indicated F_(max)−F_(a): difference between maximum and minimum of vulcameter values indicated t₁₀: juncture at which 10% of final conversion has been achieved t₅₀: juncture at which 50% of final conversion has been achieved t₉₀: juncture at which 90% of final conversion has been achieved t₉₅: juncture at which 95% of final conversion has been achieved

Vulcameter testing Compounded material No. 1 2 3 4 5 6 7 F_(a) [dNm] 3.59 4.72 4.66 6.11 4.31 4.26 5.33 F_(max) [dNm] 20.15 18.2 18.36 19.73 17.75 17.77 18.51 F_(max) − F_(a) [dNm] 16.56 13.48 13.70 13.62 13.44 13.51 13.18 t₁₀ [sec] 91 118 122 112 126 125 113 t₅₀ [sec] 188 211 213 204 217 211 202 t₉₀ [sec] 685 615 630 665 660 589 578 t₉₅ [sec] 985 878 896 940 935 883 849 t₉₀-t₁₀ [sec] 497 404 417 461 443 378 376

In the case of Examples 3, 4, and 5 of the invention, the effects of addition of gel and of silane do not include significant effects on vulcanization curve, vulcanization rate, and degrees of crosslinking.

The test specimens needed for vulcanizate characterization were obtained by press-vulcanization of the mixtures using a hydraulic pressure of 120 bar, at 160° C. The heating times for the various compounded materials are found in the this table:

Vulcanization time Compounded material No. 1 2 3 4 5 6 7 Temperature [° C.] 160 160 160 160 160 160 160 Time [min.] 21 21 21 21 21 21 21

The following table collates the vulcanizing properties of Experiments 3, 4, and 5 and of the invention, and of Comparative Experiments 1, 2, 6, and 7, which are not of the invention.

Vulcanizate properties Compounded material No. 1 2 3 4 5 6 7 Shore A hardness at 23° C. 64.9 62.4 62.3 62.7 62.1 61.1 61.3 DIN 53505 Shore A hardness at 70° C. 58.5 58 59 60 59 59 61 DIN 53505 Rebound resilience, 0° C. 9 9 9 9 9 9 9 DIN 53512 [%] [%] Rebound resilience, 23° C. 26 23 23 20 23 24 22 DIN 53512 [%] [%] Rebound resilience, 70° C. 58 61 62 62 63 62 62 DIN 53512 [%] [%] Rebound resilience, 100° C. 66 69 69 69 69 70 69 Delta R70-R23 32 38 39 42 40 38 40 Compression set, 23° C. [%] 5.6 5.01 6.01 5.23 5.68 5.59 4.53 Compression set, 70° C. [%] 14.42 14.41 14.32 14.28 15.23 15.74 14.78 σ₁₀ DIN 53504 [MPa] 0.6 0.5 0.6 0.6 0.5 0.5 0.5 σ₂₅ DIN 53504 [MPa] 1.0 0.9 0.9 1.0 0.9 0.9 0.9 σ₅₀ DIN 53504 [MPa] 1.5 1.4 1.4 1.5 1.4 1.3 1.4 σ₁₀₀ DIN 53504 [MPa] 2.6 2.7 2.8 3 2.8 2.6 2.7 σ300 DIN 53504 [MPa] 13.8 16.2 16.4 16.2 16.8 15.4 15.0 Tensile strength, 21.4 20.1 20.4 20.2 20.2 20 19.9 DIN 53504 [MPa] Elongation at break, 413 355 351 368 344 368 378 DIN 53504 [MPa] σ₃₀₀ × ε_(b) 5699 5751 6388 5962 5779 5667 5670 Abrasion, DIN 53516 [mm3] 117 116 115 113 115 121 116

Dynamic properties/Eplexor test* (heating rate: 1 K/min) Compounded material No. 1 2 3 4 5 6 7 E′ (0° C.)/10 Hz [MPa] 44.09 46.11 47.15 60.96 43.98 46.9 55.56 E″(0° C.)/10 Hz [MPa] 15.86 21.04 21.63 31.36 20.09 20.97 29.14 tan δ (0° C.)/10 Hz 0.36 0.456 0.459 0.515 0.457 0.447 0.525 E′ (60° C.)/10 Hz [MPa] 10.57 7.01 7.03 6.73 6.66 7.01 6.28 E″(60° C.)/10 Hz [MPa] 1.15 0.66 0.68 0.59 0.62 0.68 0.56 tan δ (60° C.)/10 Hz 0.109 0.095 0.096 0.088 0.093 0.098 0.09 tan δ (0° C.) − tan δ (60° C.) 0.251 0.361 0.363 0.427 0.364 0.349 0.435 *Eplexor 500 N (Gabo-Testanlagen GmbH, Ahlden, Germany)

When the vulcanizates 3, 4, and 5 produced in the invention are compared with the comparative products 1 and 2, their products σ₃₀₀×ε_(b) are found to be larger or at least equally large, without any sacrifices in terms of the differences between the rebound resilience values Δ(R70−R23), and this means that the vulcanizates produced in the invention have improved mechanical properties, without any sacrifices in terms of wet slip resistance/rolling resistance relationship.

The improvements in wet slip resistance/rolling resistance relationship are confirmed by dynamic measurements (Eplexor test). In the case of vulcanizates 3, 4, and 5, the differences found for tan δ (0° C.)−tan δ (60° C.) are greater than in the case of Comparative Experiments 1 and 2.

The sequential silanization of the invention gives the vulcanizates an improved product of modulus at 300% elongation and elongation at break (σ₃₀₀×ε_(b)), without any sacrifices in terms of the difference in the rebound resilience values Δ(R₇₀−R₂₃). 

1. A process for the production of rubber mixtures which encompasses the mixing of the following components: a) one or more rubber components, b) one or more oxidic fillers containing hydroxy groups, c) one or more microgels containing hydroxy groups, d) one or more sulfur-containing organosilicon compounds, e) if appropriate, one or more vulcanizing agents, f) if appropriate, one or more rubber additives, characterized in that the sulfur-containing organosilicon compound d) is added in at least two separate portions, where the first portion encompasses at least 30% by weight of the total amount of the sulfur-containing organosilicon compound d).
 2. The process as claimed in claim 1, which encompasses at least two mixing stages.
 3. The process as claimed in claim 1, in which the addition of the organosilicon compound d) takes place in at least two different mixing stages.
 4. The process as claimed in claim 1, which encompasses: (i) a first mixing stage, in which one or more rubber components a), one or more oxidic fillers b) containing hydroxy groups, one or more microgels c) containing hydroxy groups, one or more sulfur-containing organosilicon compounds d), if appropriate, one or more vulcanizing agents e), and also if appropriate, one or more rubber additives f) are mixed at temperatures of more than 60° C., where at least 30% by weight of the total amount of the sulfur-containing organosilicon compounds d) are added, (ii) if appropriate, cooling of the mixture obtained in the first mixing stage, (iii) a further, in particular second mixing stage, in which at least one further part of the total amount of the sulfur-containing organosilicon compounds, and also, if appropriate one or more of components a), b), c), e), and f) are added and are mixed at temperatures of more than 60° C.
 5. The process as claimed in claim 4, in which, in the further, in particular second mixing stage, the entire remaining amount of the sulfur-containing organosilicon compound d) is added.
 6. The process as claimed in claim 1, in which component c) is added in at least two separate portions.
 7. The process as claimed in claims 2, in which a part of the total amount of component c) is added in a first mixing stage, and at least one further part of the total amount of component c) is carried out in a further, in particular second mixing stage.
 8. The process as claimed in claim 7, in which, in the further, in particular second mixing stage, the entire remaining amount of component c) is added.
 9. The process as claimed in claim 1, in which the mixing in the mixing stages mentioned takes place at temperatures of more than 60° C., preferably more than 100° C.
 10. The process as claimed in claim 2, in which the mixtures are cooled between the mixing stages.
 11. The process as claimed in claim 1, in which, in a first mixing stage, from 30 to 80% by weight, more preferably from 40 to 70% by weight, of the sulfur-containing organosilicon compound d), based on the total amount of the sulfur-containing organosilicon compound used, are added.
 12. The process as claimed in claim 1, which encompasses: (i) a first mixing stage, in which one or more rubber components a), one or more oxidic fillers b) containing hydroxy groups, one or more microgels c) containing hydroxy groups, one or more sulfur-containing organosilicon compounds d), if appropriate, one or more vulcanizing agents e), and also if appropriate, one or more rubber additives f) are mixed at temperatures of more than 60° C., where at least 30% by weight of the total amount of the sulfur-containing organosilicon compounds d) are added, (ii) if appropriate, cooling of the mixture obtained in the first mixing stage, (iii) a further, in particular second mixing stage, in which at least one further part of the total amount of the sulfur-containing organosilicon compounds, and also, if appropriate one or more of components a), b), c), e), and f) are added and are mixed at temperatures of more than 60° C., (iv) cooling of the mixture obtained in step (iii), (v) a further, in particular third mixing stage, in which, as rubber additive f), one or more vulcanization accelerators, and also, if appropriate, one or more vulcanizing agents e), are added, and are mixed at temperatures which are preferably less than 60° C.
 13. The process as claimed in claim 12, in which a part of component c) is added in mixing stage (i) and the remaining part of component c) is added in mixing stage (iii).
 14. A process for the production of rubber mixtures, which encompasses the mixing of the following components: a) one or more rubber components, b) one or more oxidic fillers containing hydroxy groups, c) one or more microgels containing hydroxy groups, d) one or more sulfur-containing organosilicon compounds, e) if appropriate, one or more vulcanizing agents, f) if appropriate, one or more rubber additives, characterized in that at least two different sulfur-containing organosilicon compounds are added.
 15. A rubber mixture, obtainable as claimed in claim
 1. 16. A process for the production of vulcanizates, which encompasses the vulcanizing of the rubber mixtures as claimed in claim
 15. 17. A vulcanizate, obtainable via vulcanization of the rubber mixtures as claimed in claim
 15. 18. The vulcanizate as claimed in claim 17, in the form of tires, parts of tires, or industrial rubber items. 